walk·ing-a·round mon·ey [waw-king-uh-round]
noun
1. money that is carried on the person for routine expenses and minor emergencies; pocket money.
Source: Dictionary.com – definition of “walking around money”
The idea is that it's enough money to take care of minor needs during a routine footwalk. (If you get thirsty, you at least have enough money buy a drink, for example.)
Another phrase with a similar meaning is pin money. From NOAD:
pin money
noun
- a small sum of money for spending on inessentials.