There is no as clause; as is being used as a preposition here. As Collins has it, meaning four applies:
You use as when you are indicating what someone or something is or is thought to be, or what function they have.
The sentence you quote could be rewritten as
Do you, being this child's parent or guardian, provide your consent for the child to have access to the website?
An as statement to indicate that someone is being, speaking, acting, etc. in the capacity, role, condition, etc. of something is very common; you may have seen formulations like
As a taxpayer, I demand to know why this road is still not repaired.