Why they have different spellings although they have same pronunciation?(Iam referring to the 'ei' and 'ie' part of that words respectively)
I always get confused between them during exams.Can somebody give an easy way to remember them.
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Sure, you can follow the rule of thumb "i before e, except after c." Problem is, it's got plenty of exceptions.
vein, seize, species, science, weird, their, etc.
I know this probably isn't what you want to hear, but the only way to remember some of these idiosyncrasies of the English language is to practice and commit them to memory.
For further explanation...The word receive comes from the Anglo-Norman French receivre, so it most likely just carried its letter order over. The word relieve, however, comes from the Old French relever. Well, there's no "i" in there, so why is there one in English? There just is, I guess. If the word were spelled releve, it would likely have the same pronunciation...but for some reason we decided to throw an "i" in there.*
I know it won't help with your exams, but if it makes you feel better, plenty of native speakers frequently mix up the spelling of both of these words.
*From @hvd's comment below - it looks like the word may have had two variants in Old French: "According to http://en.wiktionary.org/wiki/relieve and http://en.wiktionary.org/wiki/relever#Old_French, it had two distinct stems in Old French, relev and reliev. The former was used for the infinitive relever, the latter was the likely source of the "i" in English".