It's often called being duck-footed or splay-footed...
As children grow, parents are often concerned about their feet pointing inwards when they walk (also called in-toe or pigeon-toed walking) or outwards (also called out-toe walking or duck-footed).
Note that splay-footed is also used to mean that the toes are more "spread out", not necessarily that the feet themselves point more "outwards".
The walking gait of someone whose feet turn outwards is also likely to be referred to as waddling (typically used specifically of how ducks themselves walk), but that term can also refer to the way a bow-legged person walks (stereotypically, an old-time cowboy who's spent too many years sitting in a saddle, forcing his legs apart).