Could you please explain me the difference between:
He is there.
There he is.
As I understand it, both phrases are used: Ngram
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'He (or she) is there' simply states that someone is at a place, but 'there he (or she) is' is drawing someone's attention to the fact that someone is somewhere visible, possibly after looking for that person. Often accompanied by a pointing gesture, and also often followed by an exclamation mark.