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Do they mean same thing? I found both use on the Internet, for example:

Why does it not work?

Why does not it work?

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    The second one ("Why does not it work?") is wrong. Remember that there are many people on the internet who are not native English speakers, or who made a typo when entering something.
    – stangdon
    Feb 25, 2022 at 15:41
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    We commonly say Why doesn't it work?, but when the words are spoken in full we always use Why does it not work?. You will see sentences like Why does not it work? in old novels, but for some reason we never use that word order nowadays. Feb 25, 2022 at 15:42

2 Answers 2

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Why doesn't it work is often used in the abbreviated form, but when not using this, you would use Why does it not work. Why does not it work is not grammatically correct.

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Why does it not work?

Why does not it work?

As commented and answered earlier, the first example is right.

englishgrammar explains further; 'contracted and uncontracted negative questions have different word order'.

Doesn’t he understand? (Auxiliary verb + n’t + subject)

Does he not understand? (Auxiliary verb + subject + not)

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