Consider a situation in which two individuals are talking — person A and person B. In the conversation, A addresses B with the phrase:
“you of all people”.
What does the phrase “you of all people” imply here, and what is its proper usage?
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It's an idiom phrase: "of all people",
of all people
— used to emphasize that a specified person is the person one most or least expects to do or know something
// You, of all people, should know the answer to this.
// My best friend, of all people, betrayed me.
used to show that you are especially surprised at a particular person's behaviour because it does not seem typical of them:
I thought that you, of all people, would believe me!
Example sentences (from The Free Dictionary)
Really, Jeff, you of all people should know that it is never OK to get behind the wheel after drinking.
And then Tom Hanks, of all people, stopped by to take pictures with our wedding party in the park.
If it's a rest they need, then why go to New York of all places?
My parents are taking us to Louisiana, of all places. What the heck is there to do in Louisiana?
When he retired, he took up painting, of all things. He had never even picked up a paintbrush before that!
After spending his childhood in and out of detention centers, he became, of all things, a cop.