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I can't figure out whether the words in question are adjectives? Do they all modify the same word at the same time? Can "something" modify the word "fierce" while "off-kilter" and "fierce" describe the collocation "color balance"?
The color balance is off-kilter something fierce, veering heavily toward the red pole of the spectrum. (The example is from Oxford Dictionaries)
"Off-kilter" is an adjective modifying the word "color balance". The phrase "something fierce", however, modifies the adjective "off-kilter": it's a colloquial way of saying "very much" or "extremely". Thus, "something fierce" would be considered to be an adverbial phrase. Some other phrases like this are "something awful" = "awfully", something terrible" = "terribly".
