Actually, those terms are defined by U.S. legislation. As noted earlier, when a river is designated into the National Wild & Scenic Rives System, it is given one of three classifications for management and protection purposes -- wild, scenic, or recreational.
Wild River Areas – Those rivers or sections of rivers that are free of impoundments and generally inaccessible except by trail, with watersheds or shorelines essentially primitive and waters unpolluted. These represent vestiges of primitive America.
Scenic River Areas – Those rivers or sections of rivers that are free of impoundments, with shorelines or watersheds still largely primitive and shorelines largely undeveloped, but accessible in places by roads.
Recreational River Areas – Those rivers or sections of rivers that are readily accessible by road or railroad, that may have some development along their shorelines, and that may have undergone some impoundment or diversion in the past.
These are defined in Section 2(b) of the Wild & Scenic Rivers Act, Public Law 90-542.
BTW: This answer was written by a member of the Interagency Wild & Scenic Rivers Council, so this should considered the definitive answer.
Scenic River Areas – Those rivers or sections of rivers that are free of impoundments, with shorelines or watersheds still largely primitive and shorelines largely undeveloped, but accessible in places by roads.
Recreational River Areas – Those rivers or sections of rivers that are readily accessible by road or railroad, that may have some development along their shorelines, and that may have undergone some impoundment or diversion in the past.