Thank you, Lord, for the teachers those who care for me.
Thank you, Lord, for the teachers who care for me.
Which of these two would be more correct?
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In the first version, "...the teachers -- those who care for me", the those-who phrase is in apposition to "the teachers" and is supplemental.
In the second version, "...the teachers who care for me", the who-clause is subordinate.
The first version is somewhat unusual; it is a stylized utterance, in a non-conversational, somewhat formal register, not inappropriate for a prayer said by a congregation. The second is normal.