Taking a cue from @snailplane, I thought I would spell out the names and pronunciations (in IPA) of all the letters of the English alphabet.
Letters beginning with a vowel sound, and so would preceded by an:
an A, the letter a, pronounced /eɪ/, beginning with the vowel /eɪ/
an E, the letter e, pronounced /iː/, beginning with the vowel /iː/
an F, the letter ef, pronounced /ɛf/, beginning with the vowel /ɛ/
an H, the letter aitch, pronounced /eɪtʃ/, beginning with the vowel /eɪ/
an I, the letter i, pronounced /aɪ/, beginning with the vowel /aɪ/
an L, the letter el, pronounced /ɛl/, beginning with the vowel /ɛ/
an M, the letter em, pronounced /ɛm/, beginning with the vowel /ɛ/
an N, the letter en, pronounced /ɛn/, beginning with the vowel /ɛ/
an O, the letter o, pronounced /oʊ/, beginning with the vowel /oʊ/
an R, the letter ar, pronounced /ɑr/, beginning with the vowel /ɑ/
an S, the letter ess, pronounced /ɛs/, beginning with the vowel /ɛ/
an X, the letter ex, pronounced /ɛks/, beginning with the vowel /ɛ/
Letters beginning with a consonant sound, and so would preceded by a:
a B, the letter bee, pronounced /biː/, beginning with the consonant /b/
a C, the letter cee, pronounced /siː/, beginning with the consonant /c/
a D, the letter dee, pronounced /diː/, beginning with the consonant /d/
a G, the letter gee, pronounced /dʒiː/, beginning with the consonant /dʒ/
a J, the letter jay, pronounced /dʒeɪ/, beginning with the consonant /dʒ/
a K, the letter kay, pronounced /keɪ/, beginning with the consonant /k/
a P, the letter pee, pronounced /piː/, beginning with the consonant /p/
a Q, the letter cue, pronounced /kjuː/, beginning with the consonant /k/
a T, the letter tee, pronounced /tiː/, beginning with the consonant /t/
a U, the letter u, pronounced /juː/, beginning with the consonant /j/
a V, the letter vee, pronounced /viː/, beginning with the consonant /v/
a W, the letter double-u, pronounced /ˈdʌbəljuː/, beginning with the consonant /d/
a Y, the letter wye, pronounced /waɪ/, beginning with the consonant /w/
a Z, the letter zee, pronounced /ziː/, beginning with the consonant /z/