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"Spill" is perfect. Yes, it is used commonly for liquid substance.

From Cambridge Dictionary

Spill: to (​cause to) ​flow, ​move, ​fall, or ​spread over the ​edge or ​outside the ​limits of something:

I spilled ​coffee on my ​silk ​shirt.
You've spilled something down ​your ​tie.
Let's ​see if I can ​pour the ​juice into the ​glass without spilling it.
He ​dropped a ​bag of ​sugar and it spilled all over the ​floor.
Crowds of ​fans spilled onto the ​field at the end of the ​game.

It's clear from the second and last two examples that whatever that was spilled, was clearly not liquid.

"Drop" is a good option, too. Suppose she has a spoon full of solid food and she drops it?

From thefreedictionary:

To cause or allow (a substance) to run or fall out of a container.

You can also say:

Don't spoil your food.

or

Be careful, don't spoil your food.

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