To be + {infinitive} means to be expected to - in the sense that there is a a plan or process and the action you are describing is the next or expected step of that plan or process (or as @user8399 says, someone has told you to do it - making it a planned activity).
To have + {infinitive} can mean this, but more often means obligated to, compelled to, forced to, or required to in a more direct sense.
My car tire blew out, I have to get it replaced. (have is appropriate)
In a week I am to attend my sister's wedding (to be + {infinitive} is appropriate)
My car tire blew out, I am to have it replaced. (bad)
My wife's car tire blew out, I am to have it replaced tomorrow. (ok)
In your example, are to pay is appropriate since normally you pay salary on expected, planned times. But most people think of payment as an obligation when they perform work, so have to pay is OK as well.
The person doing the company's payroll would more likely use are to pay and the person who hasn't gotten paid is more likely to use have to pay.