It's from the 12th episode of the 2nd season of Breaking Bad. Here is the context:
Jesse's girlfiend: He's a high-school teacher. What's he gonna do, give you a B-minus?
Send you outside to clap the erasers?
Jesse: You wouldn't really go to the cops, would you?
Jesse's girlfriend: We won't have to. He'll pay.
Jesse: And what if he doesn't?
Jesse's girfriend: Jesse, it's your money.
You're in the right here. He's in the wrong. He's not stupid. He'll pay.
What is it, really? You don't want your half a million dollars?
You wanna renounce your earthly possessions and become a monk?
Jesse: No, it's just, I'm not the kind of dude who rolls.