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The list in the subject isn't comprehensive - these are exAmples of words where an "a" is not followed by an "r", but still in Southern England (e.g. RP) people pronounce them with /ɑː/.

Are there any hints when it's the case? For example which sound I should make when pronouncing "pass" or "mass"? Are there any common etymological patterns here?

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    Some people pronounce "mass" in a religious sense with /ɑː/.
    – Colin Fine
    Commented Mar 22, 2023 at 21:18
  • @ColinFine - yes, mainly posh Catholics and High Church Anglicans ('Anglo-Catholics' like my grandma. I was resolutely Low Church until I turned atheist). Commented Mar 22, 2023 at 22:45

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Unfortunately for learners there is no rule or pattern to be found here. The "broadening" of the [a] to [ɑː] rather than flattening to [æ] always occurs before (silent) "r" (start, car) and sporadically before some fricatives (pass, father) but not always (mass, gather).

There is no rule that reliably predicts if an "a" will be broad, though the voiceless fricatives /f, θ, s/ are most likely to be preceded by a broad a, whereas the "sh" /ʃ/ is (almost) never (ash, crash).

Broadening seems to have occurred among lower-class English, mostly short common words have the broad "a", whereas long words, or words that were only used (then) in scientific or technical language don't show broadening (for example "gas" was a technical term in the 17th century)

This all means that a learner of RP pronunciation simply has to learn which words are produced with a broad "a". Fortunately, the flat "a" [æ] is very familiar (from Northern dialects and American English) so if you say [pæs] or [bæθ] you will be understood. Wikipedia has a list of words with the broad a

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